Herr Deniz Cam

Chemie

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Ich habe an der BUW meinen Bachelor- und Masterstudium in Chemie abgeschlossen. Und im Anschluss habe ich angefangen im Arbeitskreis von Prof. Dr. Carsten Jenne in der Anorganischen Chemie zu Promovieren.

 

Titel und Abstract des Dissertationsprojektes

N-Functionalization of the closo-Dodecaborate Anion [B12H12]2- via Arylation of [B12H11NH3]-

Deniz Cam, Lara Heiderich, Carsten Jenne*
(Bergische Universität Wuppertal, Anorganische Chemie, Germany)
*corresponding author: cam.deniz@uni-wuppertal.de, carsten.jenne@uni-wuppertal.de

Different ways for the N-functionalization of the closo-dodecaborate anion [B12H12]2- were developed in the past. The ammonio derivative of the closo-dodecaborate anion, [B12H11NH3]-, reacts with aryl aldehydes in methanol to N-protonated Schiff bases [B12H11NH=CHR]-.[1] We prepared and characterized a number of new derivatives with acceptor substituents (R= 4-(HO)C6H4, 4-FC6H4, 2,3-F2C6H3, 1,2-Br2-3-(HO)C6H2, 4-ClC6H4). Some of the products show interesting photo-physical properties. In addition, the direct arylation under high pressure of the ammonio cluster [B12H11NH3]- was investigated as well.

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